Synthesis and Characterization of β‐Co(OH)2, CuO and ZnO Nanostructures by Solvothermal Method without Any Additive

Abstract

Abstractβ‐Co(OH)2, CuO and ZnO nanostructures with plate‐like, particle‐like and flower‐like morphologies were prepared through the use of simple solvothermal method using of melt salt and 1,10‐phenanthroline as complexing agent and sodium hydroxide. β‐Co(OH)2 consisted of a plate‐like structure, and the nanoplates size was about 29 nm. The structure was comprised of regular sheets which were assembled together. Furthermore, the as‐obtained β‐Co(OH)2 nanoplates can be easily converted into Co3O4 nanoplates by calcining in air at 500 °C for 2 h. The results indicate that ZnO powder is of hexagonal wurtzite structure and well crystallized with high purity. CuO powder is pure monoclinic‐structured crystalline. The products were characterized by X‐ray diffraction (XRD), scanning electron microscopy (SEM), and Fourier transform infrared (FT‐IR) spectra. Possible formation mechanism of the nanostructures is proposed.