Abstract
Hybrid polyoxometalate-porphyrin copolymeric films were obtained by the electro-oxidation of zinc octaethylporphyrin (ZnOEP) in the presence of a Dawson type polyoxophosphovanadotungstate bearing two pyridyl groups (POM(py)2). The synthesis of a series of POM(py)2 consisting of [P2W15V3O62](9-) functionalized with diol-amide or triol moieties, as well as the characterization of the copolymers are presented.
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