Abstract
The complex η5,η5-(CO)3Mn(C5H4-C5H4)(CO)2Fe-η1,η5-C5H4Mn(CO)3 was synthesized by the reaction of η5-Cp(CO)2Fe-η1,η5-C5H4Mn(CO)3 with BunLi (THF, −78 °C) and then with anhydrous CuCl2. The complex μ-(C≡C)[C5H4(CO)2Fe-η1,η5-C5H4Mn(CO)3]2 was prepared by the reaction of η5-IC5H4(CO)2Fe-η1,η5-C5H4Mn(CO)3 with Me3SnC≡CSnMe3 (2:1) in the presence of Pd(MeCN)2Cl2.
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