Abstract

Cobalt ferrite–poly( N -vinyl-2-pyrrolidone) nanocomposites were prepared by drying a dispersion of cobalt ferrite (CoFe 2 O 4 ) nanoparticles and poly( N -vinyl-2-pyrrolidone). Magnetic measurements indicate a superparamagnetic behavior. Zero-field-cooling magnetization experiments at 100 Oe show different trends depending on the CoFe 2 O 4 nanoparticles size. For the smaller ones (3.9 nm), the blocking temperatures shift to lower temperatures with increasing concentration; however, this shift is not observed for the larger ones (6.6 nm). These differences can be related to the anisotropy constant of the CoFe 2 O 4 nanoparticles and the interparticle dipolar interactions.

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