Synthesis and characterization of aromatic polyamides containing s-triazine rings in the main chain

Abstract

Ten new aromatic polyamides containing s-triazine rings in the main chain were synthesized by the low temperature interfacial polycondensation technique involving the reactions of each of the two s-triazine containing diacylchlorides, viz., 2,4-bis (4-chlorocarbonylphenoxy)-6-methoxy-s-triazine and 2,4-bis(3-chlorocarbonylphenoxy)-6-methoxy-s-triazine, with five aromatic diamines namely, 4,4′-bis(4-aminophenoxy)diphenyl sulfone, 4,4′-bis(3-aminophenoxy)diphenyl sulfone, 2,2-bis[4(4-aminophenoxy) phenyl] propane, 1,4 bis (4-amino-phenoxy) benzene, and 1,3-bis (4-aminophenoxy)benzene. The resulting polyamides were characterized by viscosity measurements, IR and 1H-NMR spectroscopy, solubility tests, x-ray diffraction, and thermogravimetry. The polyamides had inherent viscosities in the range of 0.16–1.06 dL/g in N,N-dimethylacetamide at 30°C. Most of the s-triazine containing polyamides dissolved readily at room temperature in polar solvents. Except for the polyamide PA-2, the polyamides did not lose weight below 350°C under a nitrogen atmosphere. © 1997 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 35: 1077–1085, 1997