Abstract
Abstract A new inorganic-organic hybrid complex based on well-defined Keggin-type polyoxometalates and copper-lutidine assemblies, namely, [Cu3(3,5-Lutidine)6(PW12O40)]n (1), has been obtained under hydrothermal conditions and characterized by elemental analysis and single crystal X-ray diffraction. The X-ray diffraction analysis reveals that compound 1 is three-dimensional (3D) supramolecular structure with ‘sql’ topological 2D layer. The photocatalytic experiments indicate that 1 exhibit good catalytic activity for photodegradation of Rhodamine B (RhB) with UV irradiation. The thermal stabilities and fluorescent properties of this complex have also been studied.
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