Abstract
Abstract A new one-dimensional(1D) coordination polymer [Zn(MMTA) 2 ] n (MMTA=5-mercaplo-1-methyl-tetrazole) was synthesized under solvothermal conditions and characterized by single crystal X-ray diffraction. This compound crystallizes in the monoclinic space group C 2/ c , with cell parameters: a = 1.4938(7) nm, b =1.3599(5) nm, c =1.2180(4) nm, β=120.84(3) * , V =2.1243(2) nm 3 , and Z =8. The deprolonated HMMTA molecule as a μ 2 -ligand links the zinc center, forming 1D chains, which are futhcr linked by weak C—H…N hydrogen bonds, forming a three-dimensional supramolccular framework. The compound exhibits intense photoluminescence at room temperature. On the basis of the results of TG/DTA analyses, the structure is thermally stable up to −280°C.
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