Abstract

A novel 3D compound, {K3H2[Cu(Gly)2]3BW12O40}·10H2O 1 (Gly = glycine), has been synthesized and characterized by elemental analyses, IR, TG analyses, cyclic voltammetry, and single-crystal X-ray diffraction. Compound 1 contains square-grid layers constructed by potassium cations and copper-glycine coordination complexes, the [BW12O40]4− anions as templates are accommodated in the square grids by connecting with the K atoms. The K atoms link [BW12O40]4− anions from different layers together to yield a 3D novel structure. The crystal data for compounds 1: monoclinic, space group p2(1)/n, a = 18.832(4) A, b = 16.488(3) A, c = 20.570(4) A, β = 106.21(3)°, V = 6133(2) A3, Z = 4.

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