Abstract
New bismuth oxyhalides of the type BiOI 1− x Br x, form a complete solid solution series and crystallize in a layered tetragonal matlockite structure Color varies from yellow to red as x decreases from 0 75 to 0 and layer separation, c, increases from 8 45 to 9 16 Å The compounds have large intrinsic optical absorption coefficients ( α > 10 5 cm -1). Used as pigments, they are light-fast but show less color saturation than PbCrO 4 of the same hue.
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