Abstract
As part of our efforts to develop ruthenium nitrosyl compounds for use as nitric oxide delivery agents, a new six coordinate {RuNO} 6 compound, [Ru(NO)(bpb)Cl] (bpb = N, N′-bis(2-pyridinecarboxamide)-1,2-benzene dianion) was prepared from the reaction between [Ru(NO)Cl(H 2O) 2] and N, N′-bis(2-pyridine carboxamide)-1,2-benzene. We report here the characterization of this new compound by 1H, 13C, HH COSY, HMQC and HMBC NMR spectroscopy, IR spectroscopy ( ν NO = 1867 cm −1) and ESI-MS (M + Na + 505.9).
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