Abstract
AbstractThere is high demand of clean and sustainable energy where hydrogen can be an alternative instead of fossil fuel. We report here synthesis, characterization and applications of a mononuclear Ni(II) complex, [Ni(L)2] (1), with a salen type ligand, 2,2′‐((1E,1′E)‐(propane‐1,2‐diylbis(azanylylidene))bis(methanylylidene))bis(4‐bromophenol) (H2L). It has been obtained by a mild reaction with high yield. It has been characterized by the standard analytical techniques. Complex 1 has been used as an electrocatalyst in hydrogen evolution reaction where acetic acid is used as a proton source in DMF with a TOF value of 182.11 s−1. Various control experiments and results suggest the relevance of Complex 1 as the efficient electrocatalyst in the hydrogen generation from acetic acid. The metal complex has been deposited on a glassy carbon electrode and used efficiently in electrocatalytic oxidation of hydrazine.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.