Abstract
AbstractA novel energetic microporous metal‐organic coordination polymer {[Ni(tnbpdc)(bpy)(H2O)2]·1.5(DMF)}n (1) (tnbpdc = 2, 2′,6, 6′‐tetranitro‐4, 4′‐biphenyl dicarboxylate, bpy = 4, 4′‐bipyridine) was prepared solvothermally and characterized by elemental, IR spectroscopic, and single‐crystal X‐ray diffraction analyses. The X‐ray crystal structure of 1 revealed a rectangular‐shaped grid constructed with tnbpdc linkers and bpy linkers, with the free tunnel size estimated as 11 × 15 Å2. The thermal stability of the compound was evaluated by differential scanning calorimetry and thermogravimetric analysis. Such complexes may find application as novel heat‐resistant energetic materials.
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