Abstract
Graphic A cluster of four d(TG 4 T) hexanucleotides with the 3′-ends linked together by a bunchy spacer has been synthesized and shown to form a monomolecular parallel quadruplex 5 in solution characterized by four G-quartets. 1 H NMR spectroscopy and CD thermal denaturation experiments indicate the monomolecular quadruplex ( 5 ) to be more stable than the tetramolecular counterpart [d(TG 4 T)] 4 .
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