Abstract
The synthesis of two new series of diligand-tin(II) halide adducts involving piperidine and 1,4-diazabicyclo[2.2.2] octane is described. The new compounds were characterized by elemental analysis, IR and Mössbauer spectroscopy and their X-ray powder diffraction patterns are presented. The complexation isomer shifts suggest that the order of adduct stability is iodide>bromide>chloride and shifts in the NH infrared stretching frequencies are in accord with this order.
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