Abstract
A variety of new Co-substituted and Al-substituted manganese dioxide materials, having various structures, and various morphologies with nanosize crystals have been prepared by the electrochemical-hydrothermal method. The results of structural and physico-chemical characterizations are presented by comparison to non substituted MnO2 compounds. The substitution leads to nanostructured deposits with different morphologies and much larger surface areas. Intrinsic electrochemical Li insertion properties of these new substituted γ-MnO2 materials are also reported.
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