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Abstract
A new thiocyanatomolybdenum(VI) dioxo-μ-oxo complex dimer bearing a 4,4′-di-tert-butyl-2,2′-bipyridine ligand (2) is shown to exist in the crystal cell unit as a meso (Mo-O–Mo angle of 180°) and d,l, pair (Mo–O–Mo angle of 155.7°). These conformers are in equilibrium in solution and have been observed clearly by 1H NMR spectroscopy.
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