Abstract
Abstract A novel series of mono-, di-, and trifunctional monomers containing 5,6-epoxy-1,3-dioxepane groups were prepared along with a similar series of epoxycyclohexane monomers. The reactivities of the monomers were compared using both differential scanning photocalorimetry and Fourier transform real-time infrared spectroscopy. The novel monomers containing 5,6-epoxy-1,3-dioxepane groups were highly reactive in photoinitiated cationic polymerization but slightly less reactive than their counterparts based on epoxycyclohexane.
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