Abstract
A new unsymmetrical photochromic diarylethene 1-[(2-methyl-3-benzothiophene)]-2-[2-methyl-5-(1,3-dioxolane)-3-thienyl] perfluorocyclopentene (1o) has been synthesized. In the meantime, its photochromic, kinetics and fluorescence properties were investigated in detail. The results showed this compound exhibited reversible photochromism, undergoing reversible cyclization and cycloreversion reactions upon alternating irradiation with UV and visible light in solution [1]. The two isomers differ from each other not only in their absorption spectras, but also in many changes of various physical and chemical properties, such as dielectric constant, refractive index, as well as oxidation/reduction potential, etc [2]. Diarylethene 1 changed the color from colorless to pink upon irradiation with 297 nm UV light, in which absorption maxima were observed at 516 nm in acetonitrile.
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