Synthesis and adsorption performance of functionalized chitosan and carboxyethylsilanetriol hybrids

Abstract

A novel adsorbent from cationic chitosan derivative and anionic silica precursor was fabricated to remove methylene blue (MB). The hybrid material was prepared from N-guanidinium chitosan acetate (GChi) and carboxyethylsilanetriol sodium salt by a simple ionic interaction followed by sol–gel approach. Multiple characterization methods were used to analyze the morphology and the structure of the well-prepared functionalized material. Batch experiments were conducted to optimize the various operational parameters. The Langmuir isotherm was used to fit the data, and it predicted monolayer adsorption with a maximum capacity of 334 mg g−1. A pseudo-second-order equation fit the adsorption process well. Chitosan/silica hybrids containing carboxylic groups are efficient and cost-effective adsorbents for cationic dyes adsorption from aqueous solutions.