Syntheses, structures, network topologies and photoluminescence of four Zn(II) and Cd(II) coordination polymers based on 5-carboxyl-1-carboxymethyl-2-oxidopyridinium

Abstract

5-Carboxyl-1-carboxymethyl-2-oxidopyridinium (H 2CCOP) and a combination of N-donor ligands, such as 4,4′-bipyridine (4,4′-bipy) and 1,10-phenanthroline (phen) with d 10 metal ions Zn(II) and Cd(II) give rise to four coordination polymers, namely, [Zn 2(CCOP)(OH) 2(H 2O)] ( 1), [Zn(CCOP)(phen)(H 2O)]·H 2O ( 2), [Cd(CCOP)(H 2O) 2]·3H 2O ( 3), and [Cd(CCOP)(H 2O)] ( 4). Polymer 1 features an unusual bilayer motif and forms the final (3,8)-connected 3D topology by hydrogen bonds. Polymer 2 consists of one-dimensional (1D) chains which are further connected with each other via hydrogen bonds to form the final interesting (3,6)-connected rutile network. Polymer 3 is made up of an unusual 2D structure containing cylinder channels in the b axis and features the (4,4)-connected 3D network by hydrogen bonds. Polymer 4 presents an interesting uninodal 4-connected net compared to polymer 3. These four coordination polymers are obtained by evaporation or hydrothermal route and characterized by analytical, spectroscopic, and crystallographic methods. Photoluminescence studies revealed that these four coordination polymers display structure-related fluorescent emission bands ( λ ex = 342 nm) at 361 nm for polymer 1, 404 nm for polymer 2, 367 nm for polymer 3, and 371 nm for polymer 4 in the solid state at room temperature.