Abstract
A series of 3D d–f heterometallic coordination polymers, {[Ln2Zn(Pzdc)4(H2O)6]·2H2O}n [Ln = La (1), Pr (2), Nd (3), Sm (4), Eu (5), Gd (6), Tb (7), Dy (8)] (H2Pzdc = 2,3‐pyrazine dicarboxylic acid), were synthesized by one‐pot reactions under hydrothermal conditions. X‐ray crystallographical analysis and powder X‐ray diffraction analysis reveal that the complexes 1–8 are isostructural and adopt a multi‐parallel quadrilateral channel network structure with {4.6·2}2{4·2.6·2.8·2}{6·3}2{6·5.8}2 topology, in which the central LnIII ion is nine‐coordinate by four oxygen atoms and two nitrogen atoms from four ligands and three oxygen atoms from three coordinated H2O molecules and the central ZnII ion is six‐coordinate by four oxygen atoms and two nitrogen atoms from four ligands. Moreover, the photophysical properties related to the electronic transition for complexes 4, 5, 7, and 8 were investigated by the excitation and emission spectra as well as the emission lifetimes.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Zeitschrift für anorganische und allgemeine Chemie
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
