Abstract
Three azide based compounds were synthesized employing aliphatic amines as site blocking agents: [Ni(N3)(C6H16N2)2]ClO4 (I) [C6H16N2 = N,N′‐diethylethylenediamine (DEDA)], [Cu8(N3)16(C6H18N4)2] (II) [C6H18N4 = tris(2‐aminoethyl) amine (TREN)], and [Cu7(N3)14(C7H19N3)2]·2H2O (III) [C7H19N3 = 3,3′‐diamino‐N‐methyldipropylamine (DMDA)]. The compounds I and II have one‐dimensional structure and III has a two‐dimensional structure. Compound I is a simple linear cationic Ni–azide chain and compound II has Cu6 azide units forming a column terminated by the copper‐metalloligand generated in‐situ during the course of the reaction. The charge compensation perchlorate anions occupy spaces in between the chains in I. Compound II packs in a herringbone arrangement, which is not commonly observed in low‐dimensional structures. Compound III has one‐dimensional copper‐azide chains connected through copper‐metalloligand forming the two‐dimensional structure. All the three compounds exhibit anti‐ferromagnetic behavior.
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