Abstract
Two isostructural CdII frameworks, [Cd2(MMA)2(bpy)(H2O)2]n (1) and [Cd2(MMA)2(bpe)(H2O)2]n (2), were synthesized solvothermally with hybrid flexible methylmalonic acid (H2MMA) and rigid 4,4'‐bipyridine (bpy) or trans‐1,2‐bis(4‐pyridyl)ethylene (bpe) as coligands. Single‐crystal X‐ray diffraction analyses reveal that complexes 1 and 2 display a three‐dimensional (3D) framework structure composed of 2D [Cd(MMA)] layer unit and bpy/bpe linker, and exhibit a (3,4)‐connected topological network with Schläfli symbol of {63}{65.8}. The solid‐state luminescent properties were studied, and 1 and 2 show a distinct emission centered at 465 and 531 nm, respectively.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Zeitschrift für anorganische und allgemeine Chemie
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
