Abstract
Three new ternary nickel(II) coordination polymers, namely, {[Ni2(L)2(1,4-NDC)2(H2O)]·8.5H2O}n (1), {[Ni(L)(TBTA)(H2O)2]·H2O}n (2) [Ni(L)(OBA)(H2O)]n (3) (L = 1,4-bis(5,6-dimethylbenzimidazol-1-yl)-2-butylene; 1,4-H2NDC = 1,4-naphthalenedicarboxylic acid; H2TBTA = tetrabromoterephthalate; H2OBA = 4,4′-oxybis(benzoic acid)), were solvothermally synthesized and characterized. 1 exhibits an unusual 3D 3,6T13 framework. 2 and 3 both display the 2D sql networks. 1–3 have highly photocatalytic efficiency for the degradation of methylene blue by UV light irradiation. The photocatalytic mechanism was proposed, which was confirmed by trapping experiments in the presence of radical scavengers.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
