Syntheses of Ni-Based Layered-Double Hydroxide Materials Via Liquid Phase Deposition Method for Alkaline Water Electrolysis

Abstract

For the sustainable society, hydrogen production has received much attention during decades. The alkaline water electrolysis process has been recognized as one of the important processes for hydrogen products. For the achievements of an effective water electrolysis system, the decrease of the overpotential on the oxygen evolution reaction (OER), which is the four-electron and proton transfer process. These complex 4-electron sluggish processes lead to the large energy losses in the whole water electrolysis. Although the noble catalysts such as IrO2 or RuO2 exhibit high OER activity, their large-scale applications are limited due to cost problem. From this point of view, the low-cost transition metal materials, especially Ni-based catalysts, have been extensively studied. And also, it has been reported that the well-defined layered double hydroxide (LDH) structures can promote water oxidation through the interlayer anion effects. Despite this fact, the specific procedures for the preparation of Ni-based LDH structures have not been well established. Therefore, in this study, we have investigated the preparation of Ni-based LDH structures in the aqueous solution at room temperature, the so-called liquid phased deposition (LPD) method.Through the LPD method, we have synthesized various types of Ni-based LDH structures. As an example, the Ni-Al LDH structures were synthesized on the conductive substrate. It was found that our synthesized Ni-Al LDH exhibited relatively high OER activity and durability against electrochemical potential cycling [1]. In addition, the dependencies of the OER activity on the interlayer anion species were clearly demonstrated. In addition, the other types of Ni alloy LDHs were also prepared and their OER activity was investigated. Through the electrochemical measurements, we have confirmed the advantages of our materials prepared by LPD methods as an anode for alkaline water electrolysis.