Abstract
The new mixed-ligand chlororuthenium(II) complexes [RuCl(L) (tpy)]Cl n and [RuCl(L) (tpm)]Cl n (L = bpy, dmpa or dmgly; n = 0 or 1) were prepared, and the catalytic activity for alkane oxidation using m-chloroperbenzoic acid was examined. Alcohol was the main product: oxidation of adamantane, cyclooctane or ethylbenzene gave hydroxylated products, 1-adamantanol (66%), cyclooctanol (22%) or 1-phenylethanol (48%), respectively.
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