Syntheses of metal carbonyls: XVII. Formation of a heteronuclear organometallic cluster containing ruthenium and rhodium; crystal and molecular structure of {[Rh(η-C 5Me 5)] 3Ru(CO) 3](μ 3-CO) 2}

Russell P Hughes,Arnold L Rheingold,Wolfgang A Herrmann,John L Hubbard

doi:10.1016/0022-328x(85)80051-6

Syntheses of metal carbonyls: XVII. Formation of a heteronuclear organometallic cluster containing ruthenium and rhodium; crystal and molecular structure of {[Rh(η-C 5Me 5)] 3Ru(CO) 3](μ 3-CO) 2}

Russell P Hughes, Arnold L Rheingold + Show 2 more

https://doi.org/10.1016/0022-328x(85)80051-6

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Journal: Journal of Organometallic Chemistry	Publication Date: May 1, 1985
Citations: 7

Affiliation: Dartmouth College, Goethe University Frankfurt, University of Delaware

#Heteronuclear Cluster Complex #Heteronuclear Cluster + Show 8 more

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Abstract

Ru(C 6Me 6)(C 2H 4) 2 reacts with Rh(C 5Me 5)(CO) 2 to give the known dinuclear complex [Rh(C 5Me 5)(CO)] 2 and the new heteronuclear cluster complex {[Rh(C 5Me 5)] 3[Ru(CO) 3](μ 3-CO) 2} which has been fully characterized by a single crystal X-ray diffraction study.

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