Abstract
Abstract Reactions of lanthanide nitrate, 1,3,5-benzenetrisbnzoic acid (H3BTB) and [RMI]Br ionic liquids (RMI = 1-alkyl-3-methylimidazolium; R = ethyl, propyl or butyl), gave rise to six novel lanthanide–organic frameworks (LOFs) [Ln(BTB)H2O], where Ln = Nd 1, Sm 2, Gd 3, Dy 4, Ho 5 and Er 6. These compounds have been characterized by elemental analysis, IR spectra, thermogravimetric analysis, single-crystal and powder X-ray diffraction. Compounds 1–6 are isostructural and consist of infinite rod-shaped lanthanide-carboxylate building units, which are further bridged by trigonal-planar BTB ligands to give non-interpenetrated open 3D frameworks. The results of variable-temperature magnetic studies have shown that the magnetic interaction between the Ln(III) ions in 3, 5 and 6 is mainly due to antiferromagnetic coupling as well as the depopulation of the Stark levels.
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