Syntheses, crystal structures, and magnetic properties of three one-dimensional metal–nitroxide complexes linked by 1,4-cyclohexanedicarboxylate ligands

Abstract

Three one-dimensional metal–nitroxide complexes [Cu(NIT4Py)2(1,4-chdc)] n (1), {[Cu(IM4Py)2(1,4-chdc)(H2O)]·H2O} n (2) and {[Zn(IM4Py)2(1,4-chdc)(H2O)2]·H2O} n (3) (NIT4Py = 2-(4′-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide, IM4Py = 2-(4′-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl and 1,4-chdc = 1,4-cyclohexanedicarboxylate anion) have been synthesized and characterized structurally as well as magnetically. All three complexes crystallize in neutral one-dimensional chains in which the nitroxide–metal–nitroxide units are linked by linear 1,4-cyclohexanedicarboxylate anions. The 1,4-chdc ligands only present the e,e-trans-configuration in these complexes, although there are both cis- and trans-isomers in the free ligand. Magnetic measurements show that complexes 1 and 2 both exhibit weak antiferromagnetic interactions between the copper atoms and nitroxide radicals.