Abstract
Two mixed-ligand transition metal coordination polymers, {[Co(aip)(bbp)]·(H2O)} n (1) and {[Ni2(aip)(Hbbop)2]·(H2O)2} n (2) (H2aip = 5-aminoisophthalic acid, bbp = 1,3-bis(benzoimidazol-2-yl)propane, H2bbop = 1,3-bis(benzimidazol-2-yl)-2-oxapropane), were synthesized and characterized by elemental analyses, IR spectra, single-crystal X-ray diffraction, and thermogravimetric analyses. Complex 1 has a 1D chain structure, while 2 has a 3-connected 2D network with (63) topology. Both structures are further connected by hydrogen bonds and π–π stacking interactions to form the 3D supramolecular architectures. DNA binding and catalytic properties of the two complexes were investigated.
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