Abstract
Syntheses and reactions of (η 5 -(py.Me 2 B)C 5 H 4 ]ML 2 complexes (M=Rh or Co; py=pyridine; C 5 H 4 = η 5 -cyclopentadienyl) are described. Treatment of [(CO) 2 RhCl] 2 with C 5 H 5 (BMe 2 .py) or (Me 3 Si)C 5 H 4 -(BMe 2 .py) affords (η 5 -(py.Me 2 B)C 5 H 4 )Rh(CO) 2 . Reaction of (py.BMe 2 )C 5 H 5 with CO 2 (CO) 8 provides [η 5 -(py.Me 2 B)C 5 H 4 ]Co(CO) 2 . Substitution with triphenylphosphine affords [η 5 -(py.Me 2 B)C 5 H 4 ]Rh(CO)(PPh 3 )
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