Abstract

Four new heterotrinuclear complexes have been prepared and characterized, namely {[Co(L)2]2[Cu (opba)]}(ClO4)2, where opba=o-phenylenebis(oxamato) and L=1,10-phenanthroline (phen), 5-nitro-1,10-phenanthroline (NO2-phen), 2,2′-bipyridyl (bpy) and 4,4′-dimethyl-2,2′-bipyridyl (Me2bpy). The temperature dependence of the magnetic susceptibility of {[Co(phen)2]2[Cu(opba)]}(ClO4)2 has been studied in the 4–300K range, the χ MT versus T plot exhibits a minimum at ca. 131K, but abnormal magnetic behaviour below 83K.

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