Abstract

A mononuclear coordination complex, quinidinum-zinc(II)-trichloride (I), and a multi-component ionic complex, quinidinum iron(III) tetrachloride hydrogen chloride hydrate (II), have been synthesized and characterized by elemental analyses, IR spectra, and single crystal X-ray diffraction (CIF files nos. 1497628 (I) and 1497629 (II)). The weak hydrogen-bonding interactions exist in both complexes I and II. Both complexes crystallize in the chiral space groups with the absolute configuration. Complex I crystallizes in the orthorhombic space group P212121 with a = 7.6651(6), b = 11.4923(9), c = 24.653(2) A, and Z = 4. Complex II crystallizes in the monoclinic space group P21 with a = 6.6425(15), b = 18.660(4), c = 10.958(3) A, β = 104.973(3), and Z = 2.

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