Syntheses and Characterization of Three Coordination Polymers of Zinc(II) and Cadmium(II) with Dicarboxylates and Bis(thiabendazole) Ligands

Abstract

Three d10 coordination polymers formulated as [Zn(L1)2(mip)]n (1), [Zn(L1)(2,6-ndc)]n (2) and [Cd(L2)0.5(bpdc)]n (3) (L1 = 1,1′-(1,3-propanediyl)bis(thiabendazole), L2 = 1,1′-(1,6-hexanediyl)bis(thiabendazole), H2mip = 5-methylisophthalic acid, 2,6-H2ndc = 2,6-naphthalenedicarboxylic acid, H2bpdc = 4,4′-biphenyldicarboxylic acid) were hydrothermally synthesized. Complexes 1–3 were characterized by elemental analysis, IR spectroscopy, X-ray powder diffraction analysis, and single crystal X-ray diffraction. Complexes 1 and 2 present different chain structures, both of them are extended into 2D supramolecular architectures via C–H···O hydrogen bonds, while 3 is a three-fold interpenetrating three-dimensional framework with binodal 4,4-connected mog topology. The thermal stability, UV–visible spectroscopy and luminescence properties of complexes 1–3 were also examined. Furthermore, complex 3 exhibits relatively positive catalytic activity towards the degradation of methyl orange in a Fenton-like process.