Abstract
The two pentasaccharides O-(2-acetamido-2-deoxy-β- d-glucopyranosyl)- (1→2)- O-α- d-mannopyranosyl-(1→3)- O-[α- d-mannopyranosyl-(1→6)]- O-β- d- mannopyranosyl-(1→4)-2-acetamido-2-deoxy- d-glucopyranose and O-(2-acetamido-2-deoxy-β- d-glucopyranosyl)-(1→2)- O-α- d-mannopyranosyl-(1→6)-[ O-α- d-mannopyranosyl-(1→3)]- O-β- d-mannopyranosyl-(1→4)-2-acetamido-2-deoxy- d- glucopyranose which represent unsymmetrical sequences of the carbohydrate chain of N-glycoproteins of the lactosamine type and, thus, are useful compounds for studying the biosynthesis of N-glycoproteins, were synthesized by glycosidation of partially deprotected tetrasaccharides.
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