Abstract
Abstract The cationic sulfur dioxide complexes [CpFe(CO)2SO2]+AsF6- (7) and [CpCr(NO)2SO2]+AsF6- (9) are obtained in almost quantitative yield from CpFe(CO)2I(CpCr(NO)2Cl) and AgAsF6 in liquid SO2. With excess transition metal halide dinuclear halogen-bridged cations ([CpFe(CO)2IFe(CO)2Cp]+ and [CpCr(NO)2ClCr(NO)2Cp]+) are formed. The crystal structure of 7 is reported, and the bonding in the complexes is discussed in the light of spectroscopic data.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
