Abstract
Abstract Pentakis(dimethylsulfoxide)-oxo-titanium(IV) chloride is obtained by reaction of titanium tetrachloride with a stoichiometric amount of water in dimethylsulfoxide. A single crystal structure determination (P1̄, a = 9.564(6), b = 10.504(7), c = 12.510(8) Å, α = 70.21(5), β = 83.48(5), γ = 89.82(5)°, V = 1174 Å3, Z = 2) shows a dicationic titanium(IV) complex with five dimethylsulfoxide ligands and one oxygen atom. The two chlorine anions are not bonded to the complex cation. The TiO6-fragment is a distorted octahedron, where five of the six oxygen atoms belong to the coordinated dimethylsulfoxide molecules.
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