Abstract
The reaction of N-fluoroisopropylcarbamate in anhydrous HF yields the new monofluoroammonium salt NH 3F +HF 2 -·nHF. This compound may be used for the synthesis of further monofluoroammonium salts with complex fluoroanions. Mass spectroscopic investigations of volatile monofluoroammonium salts give evidence for the presence of the yet unknown monofluoramine in the gaseous phase.
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