Abstract
β-Fluoroamine compounds were obtained from 2- fluorotosylates by action of an excess of amines in dimethyl sulfoxide. The substitution of the tosyl group by amine takes place in all the studied cases whereas the elimination of toluene-p-sulphonic acid (HOTs) is not observed. This process is a good general method for the synthesis of primary, secondary and tertiary β-fluoroamines in acceptable yields.
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