Synergy between gold and oxygen vacancies in gold supported on Zr-doped ceria catalysts for the CO oxidation

Abstract

The CO oxidation activity of 1wt.% gold catalysts prepared by deposition–precipitation on a series of ceria doped with Zr supports was studied. The supports (10, 25 and 50 Zr at.%) were synthesized by a pseudo sol–gel method through the thermal decomposition of the corresponding metallic propionates. All the prepared solids were characterized by means of XRF, BET, XRD, Raman spectroscopy, SEM, and H2-TPR. Solid solution was obtained in all mixed systems, while the segregation of different Ce–Zr oxides was observed for the solid with the 50 Zr at.%. The oxygen vacancies population and the amount of easier reducible Ce4+ species in the solids increase with the Zr content. No major textural or structural modifications were detected after gold deposition, although a strong Au–support interaction was generated. Such interaction is strongly influenced by the nucleation of gold deposits on the oxygen vacancies and consequently the amount of Zr inserted in the ceria network also determines the dispersion of gold. The presence of gold eases the surface reduction at lower temperatures, and as higher the amount of Zr in the gold catalysts, higher the CO conversion at low temperatures, probably due to the enhancement of the electronic transfer at the surface of the catalysts.