Synergistic Preparation of Sludge Carbon from Oily Sludge and Walnut Shells.

Abstract

The preparation process of synergistic preparation of sludge carbon by oily sludge and walnut shells are divided into two stages: carbonization preparation of a carbon precursor and activation preparation of sludge carbon. The preparation conditions of the carbon precursor are 2.5:1 mass ratio of oily sludge and walnut shells, carbonization temperature is 450°C, and time is 2 h. There are some pores on the surface of the prepared carbon precursor, the heavy metal content of leachate does not exceed the standard, and the use process will not cause heavy metal pollution. Intensive research is carried out on factors affecting the preparation of sludge carbon by activation of the carbon precursor by the orthogonal experiment and single-factor experiment. The optimal activation conditions are determined by using ZnCl2 as an activator, mass ratio of the carbon precursor to ZnCl2 is 1:4, activation temperature is 800°C, heating rate is 15°C/min, and activation holding time is 1 h. The surface of sludge carbon is distributed with many pores, several layers of small pores can be seen deeply in the large holes, and pore size distribution is dominated by micropores and mesopores. BET Specific surface area, pore volume, average pore, and iodine value are 1772.69 m2/g, 1.98 cm3/g, 1.64 nm, and 1011.65 mg/g, respectively, which surpasses commercially available activated carbon comprehensively.