Synergistic integration of molten hydroxide direct carbon fuel cell and Stirling heat engine for efficient and clean coal use

Abstract

To reuse the exhaust heat produced by molten hydroxide direct carbon fuel cells (MHDCFCs), a new combined system mainly composed of an MHDCFC, a regenerator, and a Stirling heat engine (SHE) is theoretically integrated for fuel-to-power efficiency enhancement. Mathematical formulas of the performance indicators for the combined system are derived based on the first and second laws of thermodynamics, from which the feasibility and effectiveness of the combined system are evaluated from both energetic and exergetic viewpoints. Moreover, the optimum working regions of the combined system are further specified by using a multi-objective function paying equal attention to both efficiency and power output. Results show that SHEs can be effectively acted as bottoming cycles for MHDCFC for additional mechanical power production. Numerical calculations indicate that the maximum power density and its corresponding energy efficiency and exergy efficiency of the proposed system are, respectively, about 97.6%, 97.1% and 99.2% greater than that of the single MHDCFC. Furthermore, extensive parametric studies show that increasing working temperature, volume ratio, hot-side working substance temperature or mean pressure is beneficial for the overall system performance, while increasing reactor compartment width may degrade the overall system performance.