Synergistic extraction of uranyl ion with 1-phenyl-3-methyl-4-benzoylpyrazolone-5 (HPMBP) and diphenyl sulfoxide (DPSO), tri-n-butyl phosphate (TBP) or tri-n-octylphosphine oxide (TOPO)

Abstract

Synergistic extraction of uranyl ion with 1-phenyl-3-methyl-4-benzoyl-pyrazolone-5 (HPMBP) and oxo donors with widely varying basicity, viz. diphenyl sulfoxide (DPSO), tri-n-butyl phosphate (TBP) and tri-n-octylphosphine-oxide (TOPO) has been studied at various fixed temperatures. Results indicate that the equilibrium constants in the organic phase for addition reactions (KS) with these donors follow their order of basicity (KH) viz. DPSO (0.033)<TBP (0.16)≪TOPO (8.9) with log KS values of 3.70, 4.28 and 6.45, respectively. The thermodynamic parameters associated with the formation of these systems have been evaluted by the temperature coefficient method. The results indicate that the complex in the organic phase for DPSO and TBP is stabilized only by enthalpy, whereas both enthalpy and entropy contribute to the stabilization of the TOPO complex. Also, enthalpy contribution is more prominent as compared with the UO22+/HTTA/TOPO system, where both enthalpy and entropy contribute almost equally.