Abstract
Synergistic extraction of silver has been investigated in the presence of two different kinds of extractants, one of which is a chelating ligand, dithizone and the other is a long-chain secondary amine amberlite LA-2 at pH 3.0 using a radiotracer technique. The apparent formation constant, overall equilibrium constant and adduct formation constants were calculated from distribution coefficients. Interestingly, it was observed that the adduct formation constant is too high when the ligand concentration is increased by keeping the amine concentration fixed at 0.044 M compared to that obtained when the ligand concentration is kept fixed at 8.74×10-4 M.
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