Synergistic Effects of MOFs and Noble Metals in Photocatalytic Reactions: Mechanisms and Applications.

Abstract

Photocatalytic technology can efficiently convert solar energy to chemical energy and this process is considered as one of the green and sustainable technology for practical implementation. In recent years, metal-organic frameworks (MOFs) have attracted widespread attention due to their unique advantages and have been widely applied in the field of photocatalysis. Among them,noblemetals have contributed significant advances to the field as effective catalysts in photocatalytic reactions. Importantly, noblemetals can also form a synergistic catalytic effect with MOFs to further improve the efficiency of photocatalytic reactions.However, how to precisely control the synergistic effect between MOFs and noblemetals to improve the photocatalytic performance of materials still needs to be further studied.In this review, the synergistic effects of MOFs and noblemetal catalysts in photocatalytic reactionsare firstly summarizedin terms of noblemetal nanoparticles, noblemetal monoatoms, noblemetal compounds, and noblemetal complexes, and focus on the mechanisms and advantages of these synergistic effects, so as to provide useful guidance for the further research and application of MOFs and contribute to the development of the field of photocatalysis.