Synergistic effects of chemical composition on precipitates, dislocations, and mechanical properties of precipitation-strengthened alloys

Abstract

The properties of materials are intricately dependent on their chemical composition, and microstructures. Achieving a precise modulation in the composition and microstructure of materials to enhance properties significantly is a huge challenge. In this work, we uncovered the effects of nickel and silicon composition on the precipitates, dislocations, and properties of Cu-Ni-Si alloys. The results show that the volume fraction of precipitates increased from 0.84% to 4.80% with the increase of Ni and Si contents. The average diameter of the precipitates increased from 6.20 nm to 20.21 nm, and the dislocation density increased from 2.16×1013 m-2 to 4.08×1015 m-2 concerning the Ni and Si contents. In addition, the dislocation type changes from half-edge dislocation and half-screw dislocation to screw dislocation. The modified WHWA (Williamson Hall-Warren Averbach) method was proved to be the most accurate way of calculating dislocation density. As anisotropy was present in the alloy, adding a dislocation contrast factor and removing some lower-intensity diffraction peaks could further correct the obtained results and reduce the calculation error. Furthermore, the above analysis and findings were employed to design a Cu-3.21Ni-0.66Si alloy with a high yield strength (814 MPa), high ultimate tensile strength (970 MPa), and comparable electrical conductivity of 42.4% IACS. This work offers a meaningful way to develop precipitation-strengthening alloys.