Synergistic effect of mixing wheat straw and lignite in co-pyrolysis and steam co-gasification

Abstract

Co-pyrolysis and steam co-gasification of wheat straw (WS) and lignite coal (LC) were studied in a tube furnace between 700 °C and 900 °C. Synergistic effect in co-pyrolysis is not always apparent. However, with the introduction of H2O vapor, synergetic effect is more obvious. Gas volume generated by co-gasification was higher than the prediction in all cases. Meanwhile, temperature played an important role and had a linear relationship with the excess gas volume when it exceeded 800 °C. These findings can be explained by that sufficient H2O vapor could enhance synergy according raising catalytic effect of alkali and alkaline earth metals (AAEMs), promoting free radical generated and increasing reactivity of half-chars. Moreover, co-gasification of WS and LC with several blending ratios were studied at 850 °C. It found H2O vapor could promote free radical formation stronger with higher ratio of WS during co-gasification, thus showing an enhancing effect on the reactivity of WS-derived chars.