Synergistic effect of mixed cationic/anionic collectors on flotation and adsorption of muscovite

Abstract

Abstract The synergistic effect of the mixed cationic dodecyl amine-hydrochloride (DDA) and anionic collector sodium oleate (NaOL) at the air/water interface was investigated by the surface tension measurements. Various physicochemical properties such as surface activity parameters (CMC, γCMC, Γmax, Amin), the micellar and interfacial compositions ( X 1 m , X 1 σ ) and interaction parameters (βm, βσ) were evaluated according to the theory of regular solutions. It is observed that the mixed DDA/NaOL at αDDA = 0.5 exhibit a maximum synergistic interactions at the air/water interface. The flotation and adsorption of DDA/NaOL at the solid–liquid interface was investigated by flotation tests with muscovite, contact angle measurements and adsorption measurements. The flotation results indicate that the recovery of muscovite could be achieved a maximum value (98.45%) by the mixed DDA/NaOL at αDDA = 0.25 at pH 7.0. Contact angle measurements further confirm that the DDA/NaOL exhibit more superior hydrophobicity and collecting property than the individual DDA and NaOL. And a more pronounced synergistic effect of DDA/NaOL on muscovite surface at αDDA = 0.25 is observed, which could be attributed to a favourable arrangement of adsorbing species. The adsorption results show that the individual cationic DDA can be adsorbed strongly onto the muscovite, but no significant adsorption of anionic NaOL can be detected. However, in the mixed systems, the adsorption amounts of both DDA and NaOL are enhanced due to co-adsorption. It is proved that there is also a remarkable synergistic effect of mixed DDA/NaOL collectors at the solid–liquid interface.