Synergistic effect of ferrous ion and copper oxide on the oxidative degradation of aqueous acetaminophen at acid conditions: A mechanism investigation

Abstract

A synergistic effect of Fe(II) and copper oxide (CuO) was observed on the degradation of acetaminophen (ACT) in the presence of O2. The results showed that 89% of ACT (50mg/L) was degraded within 6h by 10mM Fe2+ with 5g/L CuO powder at pH 3.0, among which about 30% of ACT was mineralized. The sorbed Fe(II) on the CuO surface which is more reactive than the dissolved Fe(II) was capable of reducing both Cu(II) and O2. The resulting Cu(I) significantly accelerated the destruction of ACT by serving as an electron-mediator between the sorbed Fe(II) and O2. In addition, the hydrogen peroxide (H2O2), hydroxyl radical (OH) and superoxide anion radical (O2−) were identified as the main reactive oxygen species (ROSs) generated in Fe(II)/CuO suspension by Electron paramagnetic resonance (EPR) technique and quenching studies; however, only OH was found to have caused the decomposition and mineralization of ACT. First O2− was generated by reduction of O2 through a one-electron transfer pathway. Then the generated O2− mediated the production of H2O2, which further decomposed into OH by Cu(I)- and Fe(II)-catalyzed Fenton reactions. The effects of Fe(II) concentration, CuO dose, solution pH and the degradation pathway were investigated, respectively.