Synergistic Effect Enables the Dual-Metal Doped Cobalt Telluride Particles as Potential Electrocatalysts for Oxygen Evolution in Alkaline Electrolyte.

Abstract

Cobalt (Co)-based materials have been widely investigated as hopeful noble-metal-free alternatives for the oxygen evolution reaction (OER) in alkaline electrolytes, which is crucial for generating hydrogen by water electrolysis. Herein, cobalt-based telluride particles with good electronic conductivity as anodic electrocatalysts were prepared under vacuum by the solid-state strategy, which display remarkable activities toward the OER. Nickel (Ni) and iron (Fe) codoped cobalt telluride (NiFe-CoTe) exhibits an overpotential of 321 mV to achieve a current density of 10 mA cm-2 and a Tafel slope of 51.8 mV dec-1, outperforming the performances of CoTe, CoTe2, and IrO2. According to the DFT calculation, the adsorbed hydroxyl-assisted adsorbate evolution mechanism was proposed for the OER process of NiFe-CoTe, which reveals the synergetic effect toward OER induced by codoping of the Ni and Fe atoms. This work proposes a rational strategy to prepare cobalt-based tellurides as efficient OER catalysts in alkaline electrolytes, providing a new strategy to prepare and regulate metal-based tellurides for catalysis and beyond.